Equilibrium Post author By Miraj Ahmad Ansari Post date December 2, 2020 GATE CHEMISTRY Equilibrium Lesson Content 0% Complete 0/21 Steps Laws of thermodynamics Standard states Thermochemistry Thermodynamic functions and their relationships: Gibbs-Helmholtz and Maxwell relations, Gibbs-Duhem equation, van’t Hoff equation. Criteria of spontaneity and equilibrium. Absolute entropy. Partial molar quantities Thermodynamics of mixing Chemical potential. Fugacity, activity and activity coefficients. Ideal and Non-ideal solutions, Raoult’s Law and Henry’s Law, Chemical equilibria. Dependence of equilibrium constant on temperature and pressure. Ionic mobility and conductivity. Debye-Hückel limiting law. Debye-Hückel-Onsager equation Standard electrode potentials and electrochemical cells Nernst Equation and its application, relationship between Electrode potential and thermodynamic quantities, Potentiometric and conductometric titrations. Phase rule. Clausius- Clapeyron equation Phase diagram of one component systems: CO2, H2O, S; two component systems: liquid- vapour, liquid-liquid and solid-liquid systems Fractional distillation Azeotropes and eutectics Previous Lesson Back to Course Next Lesson ← Spectroscopy → Kinetics
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